The game I may be the most excited for since the new consoles came out is the Witcher III. It looks better than anything I've seen so far, and I've loved the other two games so much, this will be hard to mess up for them, in my eyes at least.
The first one was on the PC only, and I'd read that it was a 'different type' of RPG. I fell in love with that one, and then the second one I played on the 360. This time, it will be on both the new systems.
Here's the opening cinematic for the game, that they just released today.